Chem. Sq. 2019, 3, 1 This article relates the synthesis and characterization of novel heterobimetallic complexes containing a low-valent lanthanide, a tetradentate redox non-innocent ligand, viz. the 4,5,9,10-tetraazaphenanthrene, taphen ligand and transition metal…
Category: Publications
Vibrational spectroscopy of deprotonated peptides containing an acidic side chain
International Journal of Mass Spectrometry, 2019, 435, 42-50 The vibrational properties of four deprotonated dipeptides and three tripeptides containing an acidic residue, either Asp or Glu, have been studied using…
Infrared Spectra of Deprotonated Dicarboxylic Acids: IRMPD Spectroscopy and Empirical Valence-Bond Modeling
ChemPhysChem. 2019, 20(6), 803-814 Experimental infrared multiple‐photon dissociation (IRMPD) spectra recorded for a series of deprotonated dicarboxylic acids, HO2(CH2)n (n=2–4), are interpreted using a variety of computational methods. The broad bands…
New paper in J. Phys. Chem. A ! Strategy for Modeling the Infrared Spectra of Ion-Containing Water Drops
J. Phys. Chem. A 2018, 122, 3, 832-842 Hydrated ions are ubiquitous in environmental and biological media. Understanding the perturbation exerted by an ion on the water hydrogen bond network is…